Silver(I)-Catalyzed N-Trifluoroethylation of Anilines and O-Trifluoroethylation of Amides with 2,2,2-Trifluorodiazoethane.

Haiqing Luo,Guojiao Wu,Yan Zhang,Jianbo Wang

Silver(I)-Catalyzed N-Trifluoroethylation of Anilines and O-Trifluoroethylation of Amides with 2,2,2-Trifluorodiazoethane.

2016

Haiqing Luo
Guojiao Wu
Yan Zhang
Jianbo Wang

For the N-trifluoroethylation of anilines, a formal N—H insertion reaction is suggested involving a Ag(I)/carbene formation and subsequent amine ligand migratory insertion.

Keywords:

Migratory insertion
Carbene
Polymer chemistry
Amine gas treating
Chemistry
Insertion reaction
Organic chemistry
Ligand
Catalysis
amine ligands

Correction
Source
Cite
Save
Machine Reading By IdeaReader

References

Citations