Carbon nanosheets as the electrode material in supercapacitors
2009
Abstract Carbon nanosheets are comprised of 1–7 graphene layers that are predominantly vertically oriented with respect to a substrate. The thickness and morphology of the nanosheets can vary depending on the growth precursor and the substrate temperature. They have an ultra-low in-plane resistivity. The capacitance of carbon nanosheets was measured by cyclic voltammetry in a standard electrochemical three-electrode cell, which contains a platinum counter electrode and a standard mercury/mercurous sulfate reference electrode in 6 M H 2 SO 4 electrolyte. As a working electrode, the capacitance of carbon nanosheets per area was found to be 0.076 F cm −2 . A mathematical model was used to simulate the total possible capacitance of a virtual supercapacitor cell that contains carbon nanosheets as the electrode material and found to be 1.49 × 10 4 F.
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