Influence of Sediment Redox Conditions on Contaminant Stabilization by Apatite and Fe(0)

Efficacy of stabilizing Ce, Co, and Pb by adding apatite and zero-valent Fe (Fe(0)) to contaminated wetland sediments was quantified under oxidizing and reducing conditions. The redox status and the general water chemistry of the oxidized and reduced treatments differed greatly, yet the influences of the amendments on contaminant stabilization were quite similar; both amendments significantly (p less than or equal to 0.05) reduced aqueous contaminant concentrations. Based on resin sorption studies and thermodynamic calculations, Ce existed primarily as cationic and to a smaller extent, anionic species, and Co existed almost as cationic, neutral, and organically complexed species. Based on a series of varying selective extractions, almost 50 wt-percentage of the Co and Pb were already strongly bound to the sediment, thereby limiting the potential (and need) of affecting additional immobilization through the use of amendments.