Fast Desalination by Multilayered Covalent Organic Framework (COF) Nanosheets
2019
Covalent organic frameworks (COFs) are penetrated with uniform and ordered nanopores, implying their great potential in molecular/ion separations. As an imine-linked, stable COF, TpPa-1 is receiving tremendous interest for molecular sieving membranes. Theoretically, atomically thin TpPa-1 monolayers exhibit extremely high water permeance but unfortunately no rejection to ions because of its large pore sizes (~1.58 nm). COF monolayers tend to stack to form laminated multilayers, but how this stacking influence water transport and ion rejections remain unknown. Herein, we investigate the transport behavior of water and salt ions through multilayered TpPa-1 COFs by nonequilibrium molecular dynamics simulations. By analyzing both the interfacial and interior resistance for water transport we reveal that with rising stacking numbers COF multilayers exhibit increasing ion rejections at the expense of water permeance. More importantly, stacking in the offset eclipsed fashion significantly reduces the equivalent ...
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