Detection of Adsorbed Hydrogen on W(001) by Using 1H(15N, αγ)12C Reaction

Hydrogen coverage on W(001) was measured by using the resonant nuclear reaction 1H(15N, αγ)12C. The detection limit of the hydrogen coverage was 1/50 of the full monolayer, i.e. 4×1013 H atoms/cm2. The coverage dependence of the sticking probability of hydrogen was estimated by considering the ion-stimulated desorption of hydrogen. The zero-point energy of the vibration of adsorbed hydrogen atoms in the direction perpedicular to the surface was obtained by the Doppler broadening of the resonance width as 64±16 meV.