Synthesis, Detailed Characterization, and Theoretical Understanding of Mononuclear Chromium(III)‐Containing Polyoxotungstates [CrIII(HXVW7O28)2] 13‐ (X: P, As) with Exceptionally Large Magnetic Anisotropy.

Wenjing Liu,Jonathan H. Christian,Rami Al-Oweini,Bassem S. Bassil,Johan van Tol,Mihail Atanasov,Frank Neese,Naresh S. Dalal,Ulrich Kortz

Synthesis, Detailed Characterization, and Theoretical Understanding of Mononuclear Chromium(III)‐Containing Polyoxotungstates [CrIII(HXVW7O28)2] 13‐ (X: P, As) with Exceptionally Large Magnetic Anisotropy.

2014

Wenjing Liu
Jonathan H. Christian
Rami Al-Oweini
Bassem S. Bassil
Johan van Tol
Mihail Atanasov
Frank Neese
Naresh S. Dalal
Ulrich Kortz

Compounds (IV) and (VI) are characterized in the solid state by single crystal XRD, IR spectroscopy, EPR, magnetic measurements, and DFT calculations.

Keywords:

Physical chemistry
Single crystal
Electron paramagnetic resonance
Solid-state
Chromium
Magnetic anisotropy
Chemistry
Infrared spectroscopy
Inorganic chemistry
magnetic measurements

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