Die Kristallstruktur von 5-Benzoylimino-3-phenyl-2-[4-bromphenyl]-2.5-dihydro-1.2.4-thiodiazol
1972
Die von Neidlein et al. synthetisierte Verbindung C21H14BrOSN3 kristallisiert in der zentrosymmetrischen triklinen Raumgruppe P&1macr; mit den Gitterkonstanten a = 10.065 A, b = 9.858 A, c = 10.115 A, α = 104.82°, β = 77.15° und γ = 90.91°. Die Struktur wurde uber dreidimensionale Patterson- und Fourier-Synthesen ermittelt. Im Kristall liegt die Molekulstruktur 1b vor. Die gefundenen interatomaren Abstande konnen interpretiert werden, wenn man eine zusatzliche π-Bindung in der ebenen Thiodiazol-N-acylgruppe in Betracht zieht.
The Crystal Structure of 5-Benzoylimino-2-(4-bromophenyl)-3-phenyl-2.5-dihydro-1.2.4-thiodiazole
The compound C21H14BrOSN3, which was recently prepared by Neidlein et al., crystallizes in the centrosymmetric triclinic space group P&1macr; with cell dimensions a = 10.065 A, b = 9.858 A, c = 10.115 A, α = 104.82°, β = 77.15°, and γ = 90.91°. The structure was solved by the interpretation of the three-dimensional Patterson and Fourier syntheses. In the crystal the compound has the molecular structure 1b. The interatomic distances can be interpreted by assuming the existence of an additional π-bond in the thiodiazole N-acyl group.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
7
References
9
Citations
NaN
KQI