cis-1-Ethyl-4,4,6,8-tetramethyl-2-tosyl-2,3,3a,4,6,7,8,9-octahydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
2009
In the title compound, C22H29N3O5S, the pyrrolidine ring is cis-fused to the dihydropyran ring. The pyrrolidine and dihydropyran rings adopt twist and half-chair conformations, respectively. The molecule is in a folded conformation; the sulfonyl-bound benzene ring lies over the pyrimidinedione ring, with a weak π–π interaction [centroid–centroid distance = 3.6147 (4) A]. A weak intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked into a three-dimensional network by C—H⋯O hydrogen bonds.
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