1,2-Gold Carbene Transfer Empowers Regioselective Synthesis of Polysubstituted Furans
2018
A gold-catalyzed cascade cycloisomerization/ring-opening reaction of allenyl ketones bearing a cyclopropyl moiety with a wide variety of alcohols or ketones is developed. This reaction involves an unprecedented 1,2-gold carbene transfer to provide regioselective and modular access to tri- or tetrasubstituted furans in moderate to high yields and with broad substrate tolerability.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
62
References
23
Citations
NaN
KQI