A Theoretical Study of Super-Excited States of F2

In the framework of quantum defect theory, we study super-excited states of F2 molecules which can dissociate into F+(3P2,1,0) and F−(1S0) ion-pair. Based on our calculation, we present a vibrational resolved assignment of the high precision photofragment yield spectra for F− from the F2 ion-pair production.