Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction
2015
Conversion of 4-R-nitrobenzenes into 3-R-benzoic acids under the action of KCN in the EtOH–H 2 O mixture (the von Richter reaction) is significantly accelerated by ionic liquids thus allowing to extend the scope of the reaction. The finding is pioneering ionic liquid- promoted nucleophilic aromatic cine -substitution of hydrogen.
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