Metal‐Free Radical Oxidative Decarboxylation/Cyclization of Acyl Peroxides and 2‐Isocyanobiphenyls.
2015
A metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls was achieved, leading to 6-aryl phenanthridines as well as 6-alkyl phenanthridines in moderate to good yields. The procedure featured simple conditions and was metal-free and base free. It represents a practical approach to access 6-aryl/alkyl phenanthridines.
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