Water quality criteria for the protection of human health of 15 toxic metals and their human risk in surface water, China.

Abstract In the absence of water quality criteria (WQC) support for the current water quality standard (WQS), systematic WQC studies have been carried out in recent years in China. WQC for the protection of human health is established to reflect long-term consumption safety of aquatic products and water. Human health WQC for 15 toxic metals and metalloids based on exposure factors of the Chinese population and 40 field bioaccumulation factors (BAFs) were developed and analyzed in this study. Moreover, age-specific (age 2–5, 6–8, 9–11, 12–14, 15–17, and adult) and region-specific (east, central and west China) WQC were analyzed to better understanding of the impact of specific parameter values on WQC. Human health WQC with consumption of fishes and water, consumption of fishes only, and consumption of water only were derived separately. WQC with consumption of water and organism for Hg, Cd, As, Sb, Se, Zn, Co, Cu, Ni, Pb, Mn, Sn, Ba, and Sr were 0.0264, 0.710, 0.827, 3.48, 22.1, 25.7, 32.2, 32.9, 35.5, 41.8, 72.1, 97.1, 206 and 2.20 × 103 μg/L, and were 13.3 and 6.67 × 103 μg/L for Cr(VI) and Cr(III) with consumption of water only. Comparison of age-specific and region-specific WQC showed that the protection for a specific population should be considered in the development of WQC and WQS, as well as cancer effect for carcinogenic metals. Health risk analysis showed that Cd, Cu, Zn, As, Hg and Mn average concentrations in 7, 5, 9, 22, 11 and 5 provinces exceeded the WQC values with consumption of water and aquatic product, showing potential long-term health risk (HQ ≥ 1) to the local population. Therefore, health risks posed by these metals from dietary intake related to surface water should be paying more attention.