Analysis of the Structure and Conductivity of Kinked Carbon Chains Obtained by Pulsed Plasma Deposition on Various Metal Substrates

Linear-chain carbon films with a thickness of order 100 nm were studied by tunneling spectroscopy. The oscillating dependence of the differential conductivity of the investigated structures is established. The results obtained are interpreted using a model of charge-density wave formation in regular structural kinks of carbon chains. The Raman spectra of the films are recorded. The simulated spectra of harmonic oscillations of polyines (–C≡C–) n and cumulenes (=C=) n of carbon films are theoretically compared.