Kinetic and thermodynamic studies on partitioning of polychlorinated biphenyls (PCBs) between aqueous solution and modeled individual soil particle grain sizes

Abstract The significance of soil mineral properties and secondary environmental conditions such as pH, temperature, ionic strength and time in the partitioning of eight selected polychlorinated biphenyl (PCB) congeners between aqueous solution and soil particles with different grain sizes was studied. The mineral properties of a model soil sample were determined, and Brunauer–Emmett–Teller (BET) adsorption–desorption isotherms were employed to observe the surface characteristics of the individual modeled soil particles. Batch adsorption experiments were conducted to determine the sorption of PCBs onto soil particles of different sizes. The results revealed that the sorption of PCB congeners onto the soil was dependent on the amount of soil organic matter, surface area, and pore size distribution of the various individual soil particles. Low pH favored the sorption of PCBs, with maximum sorption occurring between pH 6.5 and 7.5 with an equilibration period of 8 hr. Changes in the ionic strength were found to be less significant. Low temperature favored the sorption of PCBs onto the soil compared to high temperatures. Thermodynamic studies showed that the partition coefficient ( K d ) decreased with increasing temperature, and negative and low values of Δ H ° indicated an exothermic physisorption process. The data generated is critical and will help in further understanding remediation and cleanup strategies for polluted water.