SYNTHESIS, PROPERTIES, AND STRUCTURE OF A DINITROGEN OF A DINITROGEN BRIDGED DINUCLEAR HYDRODOCOBALT COMPELX AND ITS REACTIONS WITH 1-ALKYNES

Hans-Friedrich Klein,H. Beck,Birgit Hammerschmitt,Udo Koch,S. Koppert,Gerhard Cordier,Helmut Paulus

SYNTHESIS, PROPERTIES, AND STRUCTURE OF A DINITROGEN OF A DINITROGEN BRIDGED DINUCLEAR HYDRODOCOBALT COMPELX AND ITS REACTIONS WITH 1-ALKYNES

1991

Hans-Friedrich Klein
H. Beck
Birgit Hammerschmitt
Udo Koch
S. Koppert
Gerhard Cordier
Helmut Paulus

Dinotrogen bridged cobalt (I) hydride compounds (L 3 CoH) 2 N 2 (L=PMe 3 , L=CH 3 C(CH 2 PMe 2 ) 3 have been synthesized by protonation of dinitrogen cobaltates; crystallizes in the monoclinic space group C2/m

Keywords:

Hydride
Protonation
Cobalt
Crystal structure
Reactivity (chemistry)
Molecule
X-ray crystallography
Monoclinic crystal system
Inorganic chemistry
Chemistry
Crystallography

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