Synthesis of Polycyclic Nitrogen Heterocycles via Cascade Pd-Catalyzed Alkene Carboamination/Diels-Alder Reactions
2015
Cascade Pd-catalyzed alkene carboamination/Diels–Alder reactions between bromodienes and amines bearing two pendant alkenes are described. These transformations generate 4 bonds, 3 rings, and 3–5 stereocenters to afford polycyclic nitrogen heterocycles with high diastereoselectivity.
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