Titanium Salalen Catalysts Based on cis-1,2-Diaminocyclohexane: Enantioselective Epoxidation of Terminal Non-Conjugated Olefins with H2O2.

Albrecht Berkessel,Thomas Guenther,Qifang Wang,Joerg‐M. Neudoerfl

Titanium Salalen Catalysts Based on cis-1,2-Diaminocyclohexane: Enantioselective Epoxidation of Terminal Non-Conjugated Olefins with H2O2.

2014

Albrecht Berkessel
Thomas Guenther
Qifang Wang
Joerg‐M. Neudoerfl

This describes the first synthesis of various salalen ligands based on cis-diaminocyclohexane, the characterization of their Ti complexes, and their application in Ti-catalyzed asymmetric epoxidations.

Keywords:

Conjugated system
Enantioselective synthesis
Titanium
Catalysis
Ligand
Organic chemistry
Chemistry

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