Isotope effect on the temperature dependence of the 35Cl NQR frequency in (NH4)2RuCl6
2013
Abstract The 35 Cl nuclear quadrupole resonance frequencies and spin–lattice relaxation times for (NH 4 ) 2 RuCl 6 , (ND 4 ) 2 RuCl 6 , (NH 4 ) 2 SnCl 6 , and (ND 4 ) 2 SnCl 6 were measured in the temperature range 4.2–300 K. In these four compounds, it was confirmed that no phase transition occurs in the observed temperature range. At 4.2 K, discrepancies of the NQR frequency between non-deuterated and deuterated compounds, which are attributed to the difference in the spatial distributions of hydrogen (deuterium) atoms in the ground states of the rotational motion of ammonium ion, reached to 24 kHz and 23 kHz for the ruthenate compounds and the stannate compounds, respectively. The separation between the ground and the first excited states of the rotational motion of the ammonium ion was estimated to be 466 J mol −1 and 840 J mol −1 for (ND 4 ) 2 RuCl 6 and (NH 4 ) 2 RuCl 6 , respectively, by least-square fitting calculations of temperature dependence of the NQR frequency. For (ND 4 ) 2 SnCl 6 and (NH 4 ) 2 SnCl 6 , these quantities were estimated to be 501 J mol −1 and 1544 J mol −1 , respectively. It was clarified that the T 1 minimum, which has been observed for the stannate compounds at around 60 K as a feature of the temperature dependence, was dependent on a method of sample preparation. It is concluded that the minimum is not an essential character of the ammonium hexachlorostannate(IV) since the crystals prepared in strong acid condition to prevent a partial substitution of chlorine atoms by hydroxyl groups, did not show such T 1 minimum.
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