Derivatives 1H-pyrazol halogen substituted as insecticides

2014 
Compounds of general formula (I), Formula ** ** in which R1 represents hydrogen, C1-C6 alkyl, C3-C6 alkenyl, C3-C6 alkynyl, C3-C7cycloalkyl, C1-C6 alkylcarbonyl, C1-C6, aryl- (C1-C3), heteroaryl (C1-C3) optionally substituted, M1 and M2 each independently represent hydrogen, cyano or represent C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C3 C6, C1-C6 given case mono- or polysubstituted, or M1 and M2 with the carbon atom to which they are attached form an optionally substituted ring of 3, 4, 5 or 6 membered optionally contains 0 1 or 2 nitrogen atoms and / or 0, 1 or 2 oxygen atoms and / or 0, 1 or 2 sulfur atoms, chemical groups A1 represents CR2 or nitrogen, A2 represents CR3 or nitrogen, A3 represents CR4 or nitrogen and A4 represents CR5 or nitrogen, but in which no more than three chemical groups A1 to A4 simultaneously represent nitrogen; R2, R3, R4 and R5 independently represent hydrogen, halogen, cyano, nitro, or C1-C6 alkyl, C3-C6 cycloalkyl, C1-C6 alkyl, N-alkoxy-imino C1-C6-alkyl C1-C3, alkylsulfanyl C1-C6, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, N-C1-C6 alkylamino or N, N-di-C1-C6 alkylamino optionally substituted; when neither of A2 and A3 groups is nitrogen, R3 and R4 together with the carbon atom to which they are attached, may form a 5- or 6-membered ring containing 0, 1 or 2 nitrogen atoms and / or 0 or 1 oxygen atom and / or 0 or 1 sulfur atom, or where any of the groups A1 and A2 represents nitrogen, R2 and R3 together with the carbon atom to which they are attached may form a 6-membered ring containing 0, 1 or 2 nitrogen atoms; W represents oxygen or sulfur; Q represents hydrogen, hydroxy, amino or one of the groups alkyl, alkoxy, alkenyl, alkynyl, cycloalkyl, heterocycloalkyl, cycloalkylalkyl, arylalkyl, heteroarylalkyl optionally substituted or represents a Nalquilamino, N-alkylcarbonylamino, N, N-dialkylamino group; or Q represents a carbocycle 6-membered saturated optionally monosubstituted to polysubstituted by V or represents a cyano heterocyclic 5- or 6-membered saturated optionally monosubstituted to polysubstituted with V, where V independently represents halogen, , nitro, or alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, N-alkoxyiminoalkyl, alkylsulfanyl, alkylsulfinyl, alkylsulfonyl, N, N-dialkylamino optionally substituted, T represents one of the heteroaromatic compounds of 5 members T1-T8 shown below , in union with the upper pyrazole group it is identified with an asterisk,
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