Difluorocarbene Generation from TMSCF3: Kinetics and Mechanism of NaI-Mediated, and Si-Induced, Anionic Chain Reactions

Andrés García-Domínguez,Thomas H. West,Johann J. Primozic,Katie M. Grant,Craig P. Johnston,Grant G. Cumming,Andrew G. Leach,Guy C. Lloyd Jones

Difluorocarbene Generation from TMSCF3: Kinetics and Mechanism of NaI-Mediated, and Si-Induced, Anionic Chain Reactions

2020

Andrés García-Domínguez
Thomas H. West
Johann J. Primozic
Katie M. Grant
Craig P. Johnston
Grant G. Cumming
Andrew G. Leach
Guy C. Lloyd Jones

The mechanism of CF2-transfer from TMSCF3 (1), mediated by TBAT (2–12 mol%) or by NaI (5–20 mol%), has been investigated by in situ / stopped-flow 19F NMR spectroscopic analysis of the kinetics of ...

Keywords:

Photochemistry
Difluorocarbene
Chain reaction
Chemistry
Fluorine-19 NMR
Inorganic chemistry
Kinetics
In situ

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