The standard enthalpies of formation and thermal stability of diacyldiperoxides
2012
Bomb calorimetry was used to determine the standard enthalpies of combustion and formation of eight crystalline aliphatic diacyldiperoxides with high molecular weights and low decomposition temperatures. A comparison of the calculated peroxide bond energy with the enthalpies of sublimation of these substances shows that the latter cannot in principle be determined experimentally.
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