A carbon molecular sieve membrane-based reactive separation process for pre-combustion CO2 capture

Abstract We discuss here a hybrid system combining a membrane reactor (MR) and an adsorptive reactor (AR), with the MR’s reject stream serving as the AR’s feed. We apply this system for the water gas shift (WGS) reaction for H2 generation and simultaneous CO2 capture in the context of the Integrated Gas Combined Cycle (IGCC) process for power generation from coal and biomass. This MR-AR system attains a high conversion exceeding equilibrium, produces a pure H2 product for power generation, and delivers a high-pressure CO2 stream ready for sequestration. Specifically, in our study we use carbon molecular sieve membranes (CMSMs) and a commercial sour-shift WGS catalyst. Lab experiments were carried-out to determine the membrane characteristics, and the MR performance under IGCC-relevant conditions, i.e., for temperatures up to 250⁰C and pressures up to 25 bar, employing a model coal gasifier syngas. The CMSM and the catalyst have displayed robust and stable performance during a long-term run (∼750 hr of syngas exposure). We evaluated the MR-AR system in multi-cycle runs and it has demonstrated superior performance to that of a conventional packed-bed reactor, producing a high-purity H2 product directly usable in a turbine for power generation. We conclude from the study, that the CMSM-based MR-AR system is a good candidate technology for environmentally-benign power generation. We are currently constructing a pilot-scale system for field demonstration of the technology.