Diastereoselective Palladium-Catalyzed α-Arylation of 4-Substituted Cyclohexyl Esters.
2009
A diastereoselective palladium-catalyzed arylation of 4-substituted cyclohexyl esters has been developed. The reaction proceeds at room temperature in the presence of [(t-Bu3P)PdBr]2 providing products in up to 37:1 dr.
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