Investigation of Organoiron Catalysis in Kumada–Tamao–Corriu-Type Cross-Coupling Reaction Assisted by Solution-Phase X-ray Absorption Spectroscopy

Hikaru Takaya,Sho Nakajima,Naohisa Nakagawa,Katsuhiro Isozaki,Takahiro Iwamoto,Ryuji Imayoshi,Nicholas J. Gower,Laksmikanta Adak,Takuji Hatakeyama,T. Honma,Masafumi Takagaki,Yusuke Sunada,Hideo Nagashima,Daisuke Hashizume,Osamu Takahashi,Masaharu Nakamura

Investigation of Organoiron Catalysis in Kumada–Tamao–Corriu-Type Cross-Coupling Reaction Assisted by Solution-Phase X-ray Absorption Spectroscopy

2015

Hikaru Takaya
Sho Nakajima
Naohisa Nakagawa
Katsuhiro Isozaki
Takahiro Iwamoto
Ryuji Imayoshi
Nicholas J. Gower
Laksmikanta Adak
Takuji Hatakeyama
T. Honma
Masafumi Takagaki
Yusuke Sunada
Hideo Nagashima
Daisuke Hashizume
Osamu Takahashi
Masaharu Nakamura

Solution-phase synchrotron X-ray absorption spectroscopy (XAS) is a powerful tool for structural and mechanistic investigations of paramagnetic organoiron intermediates in solution-phase reactions....

Keywords:

Inorganic chemistry
Organic chemistry
Coupling reaction
Catalysis
Photochemistry
X-ray absorption spectroscopy
Chemistry
Absorption spectroscopy
solution phase
Synchrotron
Paramagnetism

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