Interactions between ZDDP and an oil-soluble Ionic Liquid additive

Abstract Zinc dialkyldithiophosphates (ZDDP) and a P-based ionic liquid (IL) were added in a polyalphaolefin base oil (PAO). Their tribological performance in steel-steel contacts in the boundary (BL) and “starved” elastohydrodynamic (sEHL) lubrication conditions were investigated. In BL conditions, IL reduces friction at 40°C. It reduces both friction and wear at 100°C. ZDDP reduces wear but has relatively high friction at both temperatures. Synergy between IL and ZDDP is observed only at 100°C, due to the generation of a smoother worn surface and potentially a thicker boundary film. In sEHL conditions at room temperature, ZDDP, IL and their mixture change the inlet condition and increase lubricant film thickness. No synergy between the two additives is observed.