Asymmetric Aza-Claisen Rearrangement between Enantioenriched α-Chiral Allylamines and Allenones.

Rui-Han Dai,Qi Wang,Zhi-Xiong Chen,Shi-Kai Tian

Asymmetric Aza-Claisen Rearrangement between Enantioenriched α-Chiral Allylamines and Allenones.

2021

Rui-Han Dai
Qi Wang
Zhi-Xiong Chen
Shi-Kai Tian

An unprecedented asymmetric aza-Claisen rearrangement between enantioenriched α-chiral allylamines and allenones was found to proceed in the absence of catalysts and additives at room temperature. ...

Keywords:

Stereocenter
Organic chemistry
Hydrolysis
Chirality (chemistry)
Catalysis
Chemistry
Claisen rearrangement

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