Reduction of Electron Repulsion and Enhancement ofTcin Small Diffusive Superconducting Grains

The superconducting properties of small metallic grains has been a topic of active research for half a century now. Early experiments demonstrated a remarkable rise in the critical temperature, $T_{c}$, with reducing grain size in a variety of materials. In two dimensional diffusive superconductors, $T_{c}$ is decreased due to enhanced Coulomb repulsion. We propose that in finite size grains, the diffusive enhancement of the Coulomb repulsion is weakened and leads ultimately to an increase in $T_{c}$ in isolated, disordered two dimensional grains. Our mechanism is superimposed on the possible enhancement in $T_{c}$ due to the change in the density of states of finite size systems.