A SAXS Study of PHB/DGEBA Blends Crystallized at Different Temperatures☆

Abstract A small-angle X-ray scattering (SAXS) study of blends of poly-3-hydroxybutyrate (PHB)/diglycidyl ether of bisphenol A (DGEBA) with weight ratios of 90/10, 70/30 and 50/50 and PHB isothermally crystallized at temperatures between 60°C and 120°C for one hour was performed. PHB was studied at different temperatures between 30°C and 140°C. The scattering curve results (intensity as a function of scattering vector ( q )) indicated a main peak and secondary peaks associated with the thickness of the lamellae of PHB (with a strong tendency to crystallization). The position of the main peak decreased when the temperature was increased. At high temperatures (∼120°C), a deformation was observed in the main peak and a secondary peak was superimposed. This secondary peak was associated with the lamellar structures formed during the re-crystallization process. The results are discussed based on the DGEBA inclusion in the blends, crystallization temperature and partial interlamellar segregation.