Synthesis of the core bicyclic system of hyperforin and nemorosone
2003
A direct synthesis of analogs of hyperforin and nemorosone containing the key bicyclic unit was accomplished from 2-carboxyethylcyclohexanone and benzoylcyclohexanone. Key steps included a manganic acetate-mediated cyclization and the formation of the beta-bromo enone.
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