Hydrothermal Synthesis of the Oxofluoride FeSbO2F2—An Anti-ferromagnetic Spin S = 5/2 Compound
2017
The new oxofluoride compound FeSbO2F2 was synthesized by hydrothermal techniques at 230 °C. Its crystal structure was determined from single-crystal X-ray diffraction data. The compound crystallizes in the monoclinic space group C2/c with one crystallographic site for Fe3+ and Sb3+, respectively. The crystal structure is made of [FeO2F4] octahedra and seesaw [SbO4] building blocks. These are connected to form [FeO2F2]n layers and [SbO2]n chains that bond together via the oxygen atoms to form the three-dimensional framework structure. Magnetic susceptibility and heat capacity measurements indicate long-range anti-ferromagnetic ordering below a Neel temperature of ∼175 K. Two-dimensional anti-ferromagnetic short-range order in the square planar net of the Fe3+ cations extends to temperatures far above the Neel temperature.
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