Diastereoselective Self-Assembly and Crystal Structure of the Chiral, Anionic Molybdenum-Based [2+2] Molecular Square [{MoO2(C21H20O4)}2]4-
1998
The rigid geometry of the chiral spiro ligand allows not only the diastereoselective synthesis of a helical molecular square but also predetermination of the absolute configurations of the coordinated metal centers.
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