Aliphatic and aromatic C–H activation of benzo[h]quinolines by Rh(I). Unique precursor dependent formation of mono-, di- and trinuclear complexes
2011
Abstract Treatment of 7,8-benzo[h]quinoline (bhq-H, 1 ) and 10-methyl benzo[h]quinoline (bhq-Me, 3 ) with [Rh(C 2 H 4 ) 2 (THF) 2 ][BF 4 ] resulted in double C–H activation of aliphatic and aromatic C–H bonds, yielding the Rh(III) complexes 4 and 5 , respectively. The structures of 4 and 5 were revealed by X-ray diffraction. The reaction of 1 with two other slightly different rhodium precursors, [Rh(olefin) n (THF) 2 ][BF 4 ] (COE ( n = 2), COD ( n = 1)), led to completely different products, a dinuclear complex 7 and a trinuclear complex 6 , respectively, which were characterized by X-ray diffraction. Complex 6 exhibits a rare linear Rh–Rh–Rh structure. Utilizing excess of 1 with [Rh(COD)(THF) 2 ][BF 4 ] led to the formation of a new product 8 with no C–H bond activation taking place. Additional C–H activation products of 1 , cationic and neutral, in the presence of P i Pr 3 ( 9a , 9b and 10) are also presented.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
62
References
4
Citations
NaN
KQI