To Rebound or...Rebound? Evidence for the “Alternative Rebound” Mechanism in C–H Oxidations by the Systems Nonheme Mn Complex/H2O2/Carboxylic Acid

In this work, it has been shown that aliphatic C–H oxidations by bioinspired catalyst systems Mn aminopyridine complex/H2O2/carboxylic acid in acetonitrile afford predominantly a mixture of the cor...