A Novel Three-Step Tandem Reaction for Efficient Syntheses of Bulky Anthracenyl Esters from 2-Benzylbenzoic Acids

Yabai Wang,Shiwei Yang,Guangling Bian,Ling Song

A Novel Three-Step Tandem Reaction for Efficient Syntheses of Bulky Anthracenyl Esters from 2-Benzylbenzoic Acids

2017

Yabai Wang
Shiwei Yang
Guangling Bian
Ling Song

Bulky anthracenyl esters could be efficiently synthesized from 2-benzylbenzoic acids via a novel three-step tandem reaction containing intramolecular Friedel–Crafts acylation, enolization, and esterification. A mechanism for the tandem reaction is proposed.

Keywords:

Photochemistry
Acylation
Organic chemistry
Keto–enol tautomerism
Chemistry
Cascade reaction
Intramolecular force
Friedel–Crafts reaction

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