Tris[N‐(3‐chlorophenyl)pyridine‐2‐carboxamidato‐κ2N,N′]cobalt(III) monohydrate
2005
The title complex, [Co(C12H8ClN2O)3]·H2O, has been synthesized for the first time. The complex comprises three bidentate ligands containing the pyridine-2-carboxamide nucleus. The distorted octahedral coordination around the Co atom is formed via the pyridine N atom and the deprotonated amide N atom of each ligand. One intermolecular hydrogen bond forms between a carbonyl O atom of one ligand and the single water molecule.
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KQI