Biosynthetic studies of ipomeamarone

Josepf Schneider,Junning Lee,Kazuo Yoshihara,Kousei Mizukawa,Koji Nakanishi

Biosynthetic studies of ipomeamarone

1984

Josepf Schneider
Junning Lee
Kazuo Yoshihara
Kousei Mizukawa
Koji Nakanishi

Incorporation studies of deuteriomevalonates (2b–d) into ipomeamarone (1) have shown that an unusual double bond migration involving stereospecific 1,3-H-transfer takes place.

Keywords:

Double bond
Stereospecificity
Chemistry
Biosynthesis
Organic chemistry
Terpene
Ipomeamarone
Stereochemistry

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