The palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with allylic or benzylic bromides. Convenient syntheses of 1,4-alkadienes and allybenzenes from alkynes via hydroboration
1980
Abstract The reactions of allylic or benzylic bromides with 1-alkenyldisiamylboranes readily available from 1-alkynes in the presence of sodium hydroxide and catalytic amounts of tetrakis-(triphenylphosphine)palladium to give corresponding 1,4-alkadienes or allylbenzenes in good yields.
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