Phase polymorphism and electro-optical properties of a ferroelectric liquid crystal containing the biphenyl system

ABSTRACTIn this article we present results concerning phase transitions and physical properties of the ferroelectric phase of the compound (S)-4-(1-methylheptyloxy)biphenyl–4'-(heptyloxy phenyl)-4-carboxylate (MHOBOPO7). The compound has the following phases: smectic ferroelectric C (SmC*), chiral nematic N*, and two defected phases, TGBC and blue phase. The mesomorphic properties were investigated by means of three complementary methods: differential scanning calorimetry, polarizing light optical microscopy, and transmitted light intensity. The electro-optical measurements were carried out on an ordered sample in a middle electric field during very slow cooling from the nematic phase to the ferroelectric phase.