BaWO2F4: A Mixed Anion X-ray Scintillator with Excellent Photoluminescence Quantum Efficiency

A new self-activated X-ray scintillator, BaWO2F4, with an excellent photoluminescence quantum efficiency is reported. Hydrothermally grown single crystals, space group P2/n, exhibit a 3D framework structure containing isolated WO2F4 octahedra. BaWO2F4 exhibits green emission under UV light with a high quantum yield of 53% and scintillates when exposed to X-rays(Cu).