In situ growth of iron-nickel nitrides on carbon nanotubes with enhanced stability and activity for oxygen evolution reaction
2018
Abstract The efficiency of energy storage technologies such as water splitting and metal-air batteries is limited by the sluggish dynamics of the oxygen evolution reaction (OER). Herein, we report a galvanic replacement-mediated method for in-situ growth of iron-nickel nitride on carbon nanotubes (CNTs) as a powdery catalyst for OER. This in-situ grown structure creates intimate interaction between the active substance of Fe 2 Ni 2 N and CNTs so as to accelerate charge transfer in the catalytical interface. First-principles calculations reveal that the Fe 2 Ni 2 N is intrinsically metallic, and the contribution mainly derives from the Fe atoms at corner sites of crystal structures. A good synergistic effect between metallic Fe 2 Ni 2 N with excellent intrinsic activity and conductive CNTs lead to outstanding electrochemical performance with a low overpotential ( η 10 mAcm-2 = 282 mV) and Tafel slope (38 mV dec −1 ), as well as good long-term stability.
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