Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
2010
The asymmetric unit of the title compound, [K(C5HF6N2)(H2O)2]n, is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) A] and four F atoms [K—F = 2.870 (7)–3.215 (13) A]. The water molecules and the 3,5-bis(trifluoromethyl)pyrazolide anions are connected by O—H⋯N hydrogen bonds, forming layers in the ab plane. All –CF3 groups show rotational disorder between two orientations each.
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