Darzens Reaction in the Synthesis of 3-(α-Chloroalkyl)quinoxalin-2(1H)-ones.
2010
A two-stage method was developed for the synthesis of 3-(α-chloroalkyl- and α-chlorophenylalkyl)-quinoxalin-2(1H)-ones proceeding from methyl chloroalkyl- and chlorophenylalkylpyruvates obtained by Darzens reaction from methyl dichloroacetate and appropriate aldehydes in the presence of t-BuOK.
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