A New General Approach for the Stereocontrolled Synthesis of Functionalized γ‐ and δ‐Lactams.

Mark Daly,Kathryn Gill,Mairi Sime,Graham L. Simpson,Andrew Sutherland

A New General Approach for the Stereocontrolled Synthesis of Functionalized γ‐ and δ‐Lactams.

2012

Mark Daly
Kathryn Gill
Mairi Sime
Graham L. Simpson
Andrew Sutherland

A general stereoselective synthesis of functionalized γ- and δ-lactams using the Overman rearrangement to install the key C—N bond and a ring closing metathesis reaction to form the ring is developed.

Keywords:

Salt metathesis reaction
Overman rearrangement
Ring-closing metathesis
Stereoselectivity
Chemistry
Organic chemistry
pyrrole derivatives

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