Intramolecular Conjugate Addition of α,β-Unsaturated Lactones Having an Alkanenitrile Side Chain: Stereocontrolled Construction of Carbocycles with Quaternary Carbon Atoms

Fumihiko Yoshimura,Makoto Torizuka,Genki Mori,Keiji Tanino

Intramolecular Conjugate Addition of α,β-Unsaturated Lactones Having an Alkanenitrile Side Chain: Stereocontrolled Construction of Carbocycles with Quaternary Carbon Atoms

2012

Fumihiko Yoshimura
Makoto Torizuka
Genki Mori
Keiji Tanino

The efficient methodology allows the construction of carbocycles with all-carbon quarternary stereocenters from α,β-unsaturated lactones having an alkanenitrile side chain.

Keywords:

Stereocenter
Side chain
Photochemistry
Conjugate
Intramolecular force
Carbon
Atom
Michael reaction
Chemistry
Organic chemistry
Stereochemistry
quaternary carbon

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