Hydrothermal synthesis of MoS2-NiS/CdS with enhanced photocatalytic hydrogen production activity and stability

Abstract CdS is one of the most well-known photocatalysts for hydrogen production, while proper cocatalyst is indispensable to realize high hydrogen production performance. In this work, a three-component composite MoS 2 -NiS/CdS with dual cocatalysts was synthesized by a relatively facile and environmentally friendly three-step hydrothermal method and characterized by series of techniques. The as-prepared MoS 2 -NiS/CdS possesses good photostability and excellent photocatalytic hydrogen production performance. Under visible light irradiation of a 300 W Xe lamp (λ ≥ 420 nm), the H 2 production rate reached a high value of 2525.2 μmol h −1 and the total amount of H 2 evolved in 22 h achieved 40.5 mmol, further confirming that the photocatalysts with dual reduction cocatalysts possess higher photocatalytic performance than those with single cocatalyst. Especially, first study about the effect of pH of lactic acid aqueous solution on hydrogen production activity was carried out and the results indicated that increasing the pH from 1.5 to 3.0 leads to an obvious increase in H 2 -evolving activity. More importantly, an attempt on the photocatalytic hydrogen production under the irradiation of a 30 W LED lamp demonstrated that the H 2 evolved was also up to 32.1 mmol in 48 h, showing the feasibility of using cheap and long lifetime LED lamp as light source for photocatalytic hydrogen production of CdS-based photocatalysts.