Computational Investigations of Enantioselection in Carbon–Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts

Taveechai Wititsuwannakul,Tathagata Mukherjee,Michael B. Hall,John A. Gladysz

Computational Investigations of Enantioselection in Carbon–Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts

2020

Taveechai Wititsuwannakul
Tathagata Mukherjee
Michael B. Hall
John A. Gladysz

The NH2 group of 2-guanidinobenzimidazole (GBI) can be replaced by (RCRC)-NHCH(CH2)4CHNMe2 and elaborated to the enantiopure chelate salts (SRuRCRC)-[(η5-C5H5)Ru(CO)(GBICH(CH2)4CHNMe2)]+PF6– ((SRuR...

Keywords:

Enantiopure drug
Hydrogen bond
Coordination sphere
Ruthenium
Inorganic chemistry
Chelation
Catalysis
Carbon–carbon bond
Chemistry
Polymer chemistry

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