A novel pentadentate ligand 2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(II) and manganese(II) compounds; Synthesis and crystal structures of [FeL(MeCN)][ClO4](2) and [(MnL(H2O)][ClO4](2)

Maartje E. de Vries,René M. La Crois,Gerard Roelfes,Huub Kooĳman,Anthony L. Spek,Ronald Hage,Ben L. Feringa

A novel pentadentate ligand 2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(II) and manganese(II) compounds; Synthesis and crystal structures of [FeL(MeCN)][ClO4](2) and [(MnL(H2O)][ClO4](2)

1997

Maartje E. de Vries
René M. La Crois
Gerard Roelfes
Huub Kooĳman
Anthony L. Spek
Ronald Hage
Ben L. Feringa

A novel pentadentate ligand L is capable of stabilising Fe II and Mn II centres, the first of which gives a transient iron hydroperoxide species upon treatment with hydrogen peroxide.

Keywords:

Pyridine
Hydrogen peroxide
Crystal structure
Inorganic chemistry
Manganese
Chemistry
Ligand
Photochemistry

Correction
Source
Cite
Save
Machine Reading By IdeaReader

References

Citations