Low-strain titanium-based oxide electrodes for electrochemical energy storage devices: design, modification and application

Abstract To meet the growing demand for high-performance electrochemical energy storage devices, various kinds of anodes have been proposed, trying to substitute the traditional carbonous materials. Among them, low-strained Ti-based oxides (LSTBOs), especially Li4Ti5O12 and TiNb2O7, stand out for their remarkable safety and long cycling stability. Promising as they are for the high-power energy storage system, the restricted rate performance thereof owing to their poor electronic conductivity and discontented specific capacities nevertheless hinder their further commercial application. To broaden the utilization fields of LSTBOs electrodes, assorted works on the mechanism and tailing strategies have been extensively boosted to surmount these obstacles. Herein, we have summarized the latest advance and development of LSTBOs materials and application thereof in electrochemical energy storage including lithium ion batteries, sodium ion batteries, supercapacitors and hybrid capacitors. At first, a brief introduction of the properties of LSTBOs is given to help reveal the reasons for existing demerits. Then the melioration of LSTBOs themselves as well as LSTBOs devices are discussed, followed by the study of improvement mechanism of each strategy. In the end, we highlight the optimizing rules for developing advanced LSTBOs electrodes and hope that these bits of advice can serve as effective guidelines for future researches in realizing high power and high energy density devices.