A linear single-molecule magnet based on [RuIII(CN)6]3−

Kasper S. Pedersen,Jan Dreiser,Joscha Nehrkorn,Maren Gysler,Magnus Schau-Magnussen,Alexander Schnegg,Karsten Holldack,Robert Bittl,Stergios Piligkos,Høgni Weihe,Philip L. W. Tregenna-Piggott,Oliver Waldmann,Jesper Bendix

A linear single-molecule magnet based on [RuIII(CN)6]3−

2011

Kasper S. Pedersen
Jan Dreiser
Joscha Nehrkorn
Maren Gysler
Magnus Schau-Magnussen
Alexander Schnegg
Karsten Holldack
Robert Bittl
Stergios Piligkos
Høgni Weihe
Philip L. W. Tregenna-Piggott
Oliver Waldmann
Jesper Bendix

We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [RuIII(CN)6]3−. Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn–Ru exchange interactions.

Keywords:

Anisotropy
Single-molecule magnet
Magnetic susceptibility
Magnet
Chemistry
Nuclear magnetic resonance
Computational chemistry
Chemical physics
Inorganic chemistry
molecular cluster

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